四甲基碳酸氢铵的绿色合成工艺

Green Synthesis of Tetramethylammonium Hydrogen carbonate

摘要:

以碳酸二甲酯和三甲胺水溶液为原料一步合成四甲基碳酸氢铵，主要考察了原料摩尔比、反应温度、反应时间对产物收率的影响。当碳酸二甲酯与三甲胺摩尔比为1:1.2、反应温度105℃、反应时间为5h时，四甲基碳酸氢铵的收率达93.0%。

Abstract:

Tetramethylammonium hydrogen carbonate was synthesized directly from dimethyl carbonate and trimethylamine in water. The effects of materials molar ratio, reaction temperature and time on the yield of product were investigated. The optimum reaction conditions were listed as follows: dimethyl carbonate and trimethylamine molar ratio was 1:1.2, reaction temperature was 105℃, and reaction time was 5h, yielding product up to 93.0%.