RAM-相变微胶囊红外微波隐身复合材料
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TB34

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国家自然科学基金项目(面上项目,重点项目,重大项目)


RAM-MCPCM Infrared and Microwave Stealth Composites
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    摘要:

    采用种子微悬浮聚合法,以月桂酸为相变芯材,苯乙烯-二乙烯基苯共聚物为壁材,分别掺杂纳米Fe3O4和还原氧化石墨烯两种雷达吸波材料(RAM),制备了具有红外、微波兼容隐身功能的微胶囊材料(RAM-MCPCM)。采用差示扫描量热仪(DSC)、扫描电子显微镜(SEM)、振动样品磁强计(VSM)和矢量网络分析仪等对材料的形貌和性能进行了表征和测量。结果表明:采用种子微悬浮聚合法制备的相变微胶囊(MCPCM) 微观形貌呈表面光滑规则球状,芯壁质量比为1.5:1时具有最优的相变潜热和包覆率,分别为99.2J/g和57.4%;RAM-MCPCM微观形貌呈表面微凸球状,仍然具有较高相变潜热;涂层厚度0.5mm时,Fe3O4-MCPCM/环氧涂层在5.25GHz时达到最大吸收峰值-0.54dB,RGO-MCPCM/环氧涂层在8.8GHz时达到最大反射损耗-1.21 dB,两种涂层在环境温度升高时都具有一定控温作用,具备红外微波兼容隐身性能。

    Abstract:

    Microcapsules with infrared and microwave compatible stealth function (RAM-MCPCM) are prepared with the method of the seeded micro-suspension polymerization, which uses Poly(styrene-divinylbenzene) as wall material and lauric acid as core material, doping two different types of radar absorbing material (RAM), nano-Fe3O4 and reduced graphene oxide. The microstructure and properties of microcapsules are characterized and measured through differential scanning calorimeter (DSC), scanning electron microscopy (SEM), vibrating sample magnetometer (VSM) and vector network analyzer. The results indicate that the phase change microcapsules (MCPCM) prepared by the seeded micro-suspension polymerization are regularly spherical with smooth surface. With the core wall mass ratio of 1.5:1, the MCPCM have the best the latent heat of phase change and encapsulation ratio, 99.2J/g and 57.4% respectively. The morphology of the RAM-MCPCM which still have relatively high latent heat of phase change are a slightly convex spherical surface. With the coating thickness of 0.5mm The Fe3O4-MCPCM/epoxy coating at 5.25GHz reaches the maximum absorption peak of -0.54dB and the RGO-MCPCM/epoxy coating at 8.8GHz reaches maximum reflectivity of -1.21dB. Two types of coatings have a certain temperature control effect when the ambient temperature is elevated and they have the function of infrared and microwave compatible stealth.

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崔锦峰,邵竞尧,许芬,郭军红,慕波,杨保平. RAM-相变微胶囊红外微波隐身复合材料[J].精细化工,2017,34(12):

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  • 收稿日期:2017-01-11
  • 最后修改日期:2017-04-12
  • 录用日期:2017-05-26
  • 在线发布日期: 2017-11-10
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