醇绿色催化氧化方法研究进展

Progress in catalytic oxidation of alcohols with eco-friendly oxidants

摘要:

伯醇和仲醇被氧化为相应的羰基化合物是重要的官能团转换反应，目前主要通过催化的方法来实现。随着绿色化学的发展，采用环境友好的氧化剂开发新的催化氧化方法实现醇的氧化是近年来的研究热点。本文综述了2000年以来以氧气、过氧化氢以及丙酮作为氧化剂催化氧化醇研究的进展，并对不同方法的特点进行了总结，据此指出了后期绿色催化氧化醇的发展方向。

Abstract:

The oxidation of primary and secondary alcohols to corresponding carbonyl compounds is an important functional group conversion, which is mainly achieved by catalyst. The importance of eliminating waste production and development of green process using eco-friendly oxidants to oxidize alcohols attracts much research interests. The research progress in the catalytic oxidation of alcohols using eco-friendly ox-idants such as oxygen, hydrogen peroxide and acetone since 2000 was reviewed. At the same time, the characteristics of different methods were summarized. The development trend of green catalytic oxidation of alcohols was presented.