三聚氰胺树脂作为碳基材料前驱体在电化学储能电极材料中的研究进展

Research progress of carbon-based material of melamine resin as precursor in electrochemical energy storage electrode materials

摘要:

电极材料是影响电化学储能系统性能的主要因素，目前，对其性能改善的研究主要集中于结构的优化和杂原子的引入两个方面。以三聚氰胺树脂为前驱体制备的碳基材料凭借其丰富的孔道结构和高含量的氮原子掺杂双重优势，在电化学储能设备的电极材料的应用中表现出高电容性能和出色的循环能力。本文从活化法、模板碳化法、混合聚合物碳化法等孔道控制工艺，探讨了孔道结构对于材料性能的影响。针对当前主流研发的电池和超级电容器，对以三聚氰胺树脂为原料制备的碳基材料展开综述，并分析其研究现状与发展趋势。

Abstract:

Electrode materials are the principal factor, which of affecting electrochemical energy storage system performance, nowadays, research on the improvement of performances is focused on structural optimization and introduction of heteroatom. Carbon-based material, which is prepared by melamine resin as precursor, has excellent capacitive performance and recycle ability in the application of electrode materials of electrochemical energy storage, due to its ample open-framework structure and nitrogen atoms doping. This paper discusses the influence of porous structure on material performance from the porous control method such as activation method, template-carbonization method, and mixed polymer carbonization method. Meanwhile, this paper reviews the carbon-based material which prepared by melamine resin as precursor, and analyzes its research status and development trend for current battery and super capacitor.