三苯乙烯基苯酚聚氧乙烯醚硫酸酯盐分散剂在液体分散染料制备中的应用

Preparation and application of styrene-based anionic dispersant

摘要:

以不同环氧乙烷（EO）数的三苯乙烯基苯酚聚氧乙烯醚（TSPOE）为反应物，氨基磺酸为硫酸化试剂，尿素为催化剂，合成了系列三苯乙烯基苯酚聚氧乙烯醚硫酸酯盐（TSPOES）。利用TSPOES为分散剂制备了液体分散染料，通过粒径分析探究了液体分散染料的储存稳定性，优选储存稳定好的液体分散染料研究了其染色性能。结果表明，TSPOE与氨基磺酸的摩尔比为1：1.6时，阴离子活性物（TSPOES）含量均在85%以上。分散剂TSPOES中EO数增大，制备的液体分散染料粒径和PDI呈先降低后增大趋势，当分散剂TSPOES中的EO数为20时，制备的液体分散染料粒径为165.9 nm、PDI为0.195，储存稳定性最好。将其用于高温染色时，染色匀染性好，且染色后织物无需还原清洗耐摩擦色牢度仍达4-5级。

Abstract:

A series of tristyryl phenol polyoxyethylene ether sulfates salt (TSPOES) with different ethylene oxide (EO) numbers were synthesized with tristyryl phenol polyoxyethylene ethers (TSPOE), sulfamic acid and urea as original materials. Liquid disperse dyes were prepared using TSPOES as dispersant, and the storage stability of liquid disperse dyes was explored through particle size analysis, then the dyeing properties of liquid disperse dyes with good storage stability were explored. The results showed that the content of anionic active substances（ TSPOES )was above 85% when the molar ratio of TSPOE to sulfamic acid was 1:1.6. With increasing of the EO number of dispersant TSPOES, the particle size and PDI of the prepared liquid disperse dyes decreased first and then increase. When the EO number of dispersant TSPOES was 20, the particle size of the prepared liquid disperse dyes was 165.9 nm, the according PDI was 0.195. At the same time, its storage stability