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甲醇氧化羰基化合成碳酸二甲酯催化剂研究进展
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作者单位:

成都信息工程大学资源环境学院

基金项目:

四川省科技计划资助(2021YFG0225,2021ZHZY0006)、成都信息工程大学科研基金资助成果(编号KYTZ202118)


The Progress of Catalysts for Methanol Oxidation Carbonylation to Dimethyl Carbonate
Author:
Affiliation:

China-Serbia “the Belt and Road” Joint Laboratory on Environment and Energy,College of Resources and Environment,Chengdu University of Information Technology CUIT

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    摘要:

    碳酸二甲酯(DMC)是一种用途广泛的绿色化工原料。甲醇氧化羰基化法合成DMC具有产品选择性高、反应温度低、原子经济等优点,是合成DMC最重要的方法之一。综述了甲醇氧化羰基化合成DMC催化剂的研究进展,包括含卤素铜系催化剂和无卤素铜系催化剂,重点讨论了无卤素铜系催化剂的反应机理及活性炭、石墨烯和分子筛等载体对催化性能的影响。分析发现,载体中的介孔结构、缺陷位和表面基团能够加强Cu与载体间的相互作用,抑制Cu物种的团聚、流失以及活性Cu物种氧化,从而提高催化性能。

    Abstract:

    Dimethyl carbonate (DMC) is a widely used as green chemical raw material. Methanol oxidation carbonylation synthesis of DMC is one of the most important synthesis methods of DMC, which has the advantages of high product selectivity, low reaction temperature, atomic economy. The progress of halogen containing copper catalyst and halogen free copper catalyst for methanol oxidation carbonylation to dimethyl carbonate is reviewed. The reaction mechanism of halogen-free catalysts and the influence of activated carbon, graphene and molecular sieve on catalytic performance are discussed emphatically. It was found that the mesoporous structure, defect sites and surface groups in the support could enhance the interaction between Cu and the support, also could inhibit the agglomeration and loss of Cu species and the oxidation of active Cu species, thus the catalytic performance was improved.

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邓志勇,李文杰,林慧博,王馨雨,刘源.甲醇氧化羰基化合成碳酸二甲酯催化剂研究进展[J].精细化工,2022,39(11):

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  • 收稿日期:2022-05-03
  • 最后修改日期:2022-09-03
  • 录用日期:2022-09-05
  • 在线发布日期: 2022-09-30
  • 出版日期: 2022-09-30
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