金属-有机框架材料在硅氢加成反应中的应用研究进展

Research progress on the application of metal-organic frameworks in hydrosilylation reactions

摘要:

硅氢加成反应是指在一定条件下含有硅氢键的化合物与含不饱和键的化合物进行的加成反应，是构筑C-Si键的重要反应之一，在有机硅工业中具有举足轻重的地位。本文综述了近年来金属-有机框架化合物（MOFs）催化此类反应的研究工作，并针对每一种反应底物进行的反应系统地进行了总结与评述，最后对MOFs材料用于催化硅氢加成反应进行了展望。

Abstract:

Hydrosilylation reaction refers to the addition reaction of compounds containing Si-H bonds and compounds containing unsaturated bonds under certain conditions. It is one of the important reactions for building C-Si bonds and plays an important role in the silicone industry. In this paper, the recent research work on metal-organic frameworks (MOFs) catalyzing such reactions is reviewed, and the reactions carried out by each reaction substrate are systematically summarized and reviewed. Finally, the prospect of MOFs for catalyzing hydrosilylation reaction is given.